Endura Dual Steel – Ultimate Wear-Resistant Steel

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ENDURA Dual (Impact + Abrasion Resistance)

Same performance as Carbide Overlay at 1/2 the price!

ENDURA Dual is an advanced abrasion-resistant steel additionally alloyed with “High Titanium Carbines” (0.6%). This innovative grade is mainly dedicated to “Sever Sliding” abrasion where conventional water quenched steels (500HB, 550HB), hardfacing plates or hard-cast parts are traditionally used. Compared to ENDURA, ENDURA Dual capitalizes upon an innovative metallurgical concept, and a unique chemical formulation. It is produced by Oil Quenching, which reduces the level of the residual stresses that is encountered within the plate after heat treatment, compared to more drastic water quenching.

Similar to ENDURA, ENDURA Dual also has unique “Work Hardening” properties. With impact, ENDURA will “work harden” from 480 BHN to 560 BHN.

The outstanding extra wear resistance, combined with high impact cycle load, is mainly due to the contribution of the following hardening phenomena:

An homogeneous precipitation of extra hard primary “Titanium Carbides” in the steel matrix leads to a significant improvement of the sliding wear resistance in extreme service conditions
A superficial hardening following a very efficient work hardening capability in service, governed by a metallurgic phenomenon called TRIP effect (Transformation Induced by Plasticity).
In addition to a high stress grinding abrasion resistance, an ability of forming also remains within reasonable limits and allows the processing of curved parts (Fig 1, Fig 2 : ENDURA Dual, 2000x300x10mm, Rint=1000mm)

No other competitor offers wear resistant steel at this level of hardness 500HB, with such high abrasion resistance combined with high resistance to cracking in service!

Standard

Chemical Composition

C	Mn	Ni	Cr	Mo	S	P
≈ 0.40	≈ 1.30	≈ 0.45	≈ 0.70	≤ 0.340	≤ 0.002	≈ 0.60

Mechanical Properties (Indicative Values as Delivered)

Hardness (HB)	Yield	Tensile 20°C (68°F)	Elongation	Chappy KCVL -4°F (-20°C)
480 -> 560 (50 -> 55 RCH)	174 Ksi (1200 Mpa)	236 Ksi (1630 Mpa)	10% 10%	> 18 ft. lbs. (> 24 J/cm2)

Physical Properties Expansion coefficient (x 10-6.°C-1)

20/100°C 68/212°F	20/200°C 68/392°F	20/300°C 68/572°F	20/400°C 68/732°F	20/500°C 68/932°F
11.2	12.0	12.5	13.2	13.8

Metallurgical Concept

Wear resistance depends not only on the hardness of the steel at delivered state, but also on other properties, such as crack resistance, work hardening effect, strength, ductility, softening resistance, etc.

The performance in service of given wear resistant steel is strongly influenced by the microstructure obtained after thermal processing. In the case of ENDURA Dual, a significant improvement of the wear resistance in service is mainly due to the following properties:

"TRIP effect": Transformation Induced by Plasticity

As its initial structure not fully martensite (a mix of martensite, bainite and retained austenite), ENDURA Dual has the ability to work-harden when submitted to local plastic deformation in service. Plastic deformation induces a surface hardening phenomenon by transformation of retained austenite into fresh and very hard martensite while the material remains ductile underneath, making it most effective to withstand both abrasion and heavy impact in service.

In addition, the super ductility of the retained austenite contributes to improve the lifetime in service by allowing larger micro shearing and thus delays the ultimate tearing of metal particles from the surface of the material exposed to the abrasive.

On this typical microstructure of ENDURA grades, the retained austenite grains revealed by means of Klemm reactive etching appear in white. When subjected to plastic deformation in service (impact or high pressure), ENDURA®Dual takes advantage of a surface hardening about 70 HB, whatever the applied strain level.

Titanium Carbides

The extreme abrasion resistance versus the conventional wear resistant steels (500HB, 550HB…) is gained by the presence of the primary titanium carbides which are precipitated during the first stage of the solidification (already present within the semi-products, slab or ingot, before rolling and heat treatment). These titanium carbides exhibit an average hardness of 3000HV (Vickers hardness) and therefore create numerous hard spots in the steel matrix like crushed gravel in concrete.

Extremely hard primary titanium carbides homogeneously embedded in the steel matrix

Abrasive Wear Test Results

Properties at High Temperature

Chemical composition of ENDURA Dual, and specially chromium, molybdenum and huge titanium contents, give a high softening resistance to the material. This property allows using ENDURA Dual in hot service conditions, at a maximum of 450°C (840°F) while conventional 500 HB water quenched steels are limited to 250°C (480°F).

Service Life

Whatever service conditions are, the original metallurgical concept of ENDURA Dual gives the material an improve of its performance in terms of wear resistance and process ability, compared to other conventional 500 HB water quenched steels, especially for extreme applications, where severe abrasion conditions are combined with huge impact, heat or moderate corrosion.

Processing

Cutting

All classical thermal processes (gas-plasma-laser) can be used. Plasma/laser processes are specially recommended. They provide increased precision and cutting aspect and induce a thinner Heat Affected Zone (HAZ).

Welding

ENDURA Dual can be welded with all classical processes: manual (SMAW), semi-automatic under gas protection (GMAW), automatic under flux (FCAW). Welded areas shall be clean, free of grease, water, and oxides. Electrodes and flux shall be dried according to supplier’s recommendations. For welds without preheating, an austenitic welding wire shall be used. Following welding conditions have been used in our weld tests:

	Solid Wire	Gas
Trademark	LNM 307	ATAL 5A
Standard name	ER307 / G18-8-Mn	M21
Supplier	Lincoln	Air Liquid
Diameter/Composition	Ø 1.2 mm	82% Ar+18% C02
Automatic/Manual	Automatic
Welding position	PB
Heat Input (KJ/cm)	12 – 18
Voltage (V)	26 – 28
Amperage (A)	220 – 270
Travel speed (cm/min)	25 – 35
Polarity	DC+
Wire feed rate (m/min)	10 – 12
Gas flow rate (l/min)	18 – 24
Stick-out (mm)	10 – 20
Preheating (°C)	20°C
Interpass temp. (°C)	40°C

If you are using a ferritic welding product, preheating is strongly recommended in order to avoid cold cracking defects. The following welding conditions have been used in our weld tests:

	Solid Wire	Gas
Trademark	Nertalic 70A	ARCAL 12
Standard name	A5.18 / G3Si1	M12
Supplier	SAF	Air Liquid
Diameter/Composition	Ø 1.2 mm	98% Ar+2% C02
Automatic/Manual	Automatic
Welding position	PB
Heat Input (KJ/cm)	12 – 18
Voltage (V)	26 – 28
Amperage (A)	220 – 270
Travel speed (cm/min)	25 – 30
Polarity	DC+
Wire feed rate (m/min)	7.5
Gas flow rate (l/min)	18 – 24
Stick-out (mm)	10 – 20
Preheating (°C)	160°C
Interpass temp. (°C)	180°C

Forming and Machining

Refer to the ENDURA Dual guideline.

Applications

The properties of ENDURA Dual clearly indicate that this steel has many potential applications where an extreme abrasion resistance combined with high resistance to cracking is required in service, such as:

Bucket liners for excavator, shovel, loader, dozer
Cutting edges and stiffeners for different types of buckets
Truck tray body liners
Wear parts for primary and secondary crushers
Vibratory feeder liners
Chute liners
Hopper liners
Screens
Trommels
Pipe elbows
Cyclones
Deflectors
Grinder liners (SAG Mill)
Demolition tools (recycling)
Pipes for dredging
Blade liners for heavy duty fans

Examples of three areas of industry where ENDURA Dual can make the different versus the conventional solutions…

Counter-Blades: Mines & Quarries

Extra Large Fans (XXL), Extreme Service Conditions (blade protection)

Screens (hot working conditions)

· cement plants

· incineration plant (waste treatment technology)

· ore processing

· iron making plants

· iron making plant (blast furnace)

· sintering plant

· coking plant

In general, for complex applications where the wear phenomenon is combined with high temperature or corrosion, the service conditions should be carefully investigated in order to provide adequate solution…

Dimension Programme

Sizes – mm (inch)	Thickness – mm (inch) 9.5 to 50 mm (0.375 to 1.968)
2000 x 6000 (78.740 x 236.220)	xx
2500 x 8000 (98.425 x 314.960)	xx

xx=optimum sizes

Indicative dimensional programme

Other dimensions available on request.

Please note: This technical data and information represents our best knowledge at the time of printing. However, it may be subject to some slight variations due to our ongoing research programme on abrasion resistant grades. We therefore suggest that information be verified at time of inquiry or order. Furthermore, in service, real conditions are specific for each application. The data presented here is only for the purpose of description, and may only be considered as guarantees when our company has given written formal approval. 2. ENDURA DUAL has been developed specifically for its abrasion resistance. Customer’s usage of ENDURA DUAL for any other purposes, not directly resulting from its abrasion resistance, is his own prerogative but won’t, in any way, engage TITUS STEEL’s responsibility. In addition to the recommendations given in this document, customer will have to follow the industry standard quality rules for any processing operation performed on this material.

ENDURA Dual